One annoying piece of Unity's CoreCLR plan is there is no plan to upgrade IL2CPP (Unity's AOT compiler) to use a better garbage collector. It will continue to use Boehm GC, which is so much worse for games.
They just haven't announced any plans to do so yet. They might one day.
They will not be using .NET AOT probably ever though. Unity's AOT basically supports full C# (reflection etc) while .NET opted to restrict it and lean more on generated code.